How you date a rock depends on what type of rock it is and how old it might be. Different radioactive isotopes have different half lives and so they are useful for dating different types and ages of rocks. Who would want to? Why, geologists, of course!

Radiometric dating is the process of using the concentrations of radioactive substances and daughter products to estimate the age of a material. Different isotopes are used to date materials of different ages. Using more than one isotope helps scientists to check the accuracy of the ages that they calculate.

Radiocarbon dating is used to find the age of once-living materials between 100 and 50,000 years old. This range is especially useful for determining ages of human fossils and habitation sites (Figure below).

Carbon isotopes from the black material in these cave paintings places their creating at about 26,000 to 27,000 years BP (before present).

The atmosphere contains three isotopes of carbon: carbon-12, carbon-13 and carbon-14. Only carbon-14 is radioactive; it has a half-life of 5,730 years. The amount of carbon-14 in the atmosphere is tiny and has been relatively stable through time.

Plants remove all three isotopes of carbon from the atmosphere during photosynthesis. Animalsconsume this carbon when they eat plants or other animals that have eaten plants. After the organism’s death, the carbon-14 decays to stable nitrogen-14 by releasing a beta particle. The nitrogen atoms are lost to the atmosphere, but the amount of carbon-14 that has decayed can be estimated by measuring the proportion of radioactive carbon-14 to stable carbon-12. As time passes, the amount of carbon-14 decreases relative to the amount of carbon-12.

Potassium-40 decays to argon-40 with a half-life of 1.26 billion years. Argon is a gas so it can escape from molten magma, meaning that any argon that is found in an igneous crystal probably formed as a result of the decay of potassium-40. Measuring the ratio of potassium-40 to argon-40 yields a good estimate of the age of that crystal.

Potassium is common in many minerals, such as feldspar, mica, and amphibole. With its half-life, the technique is used to date rocks from 100,000 years to over a billion years old. The technique has been useful for dating fairly young geological materials and deposits containing the bones of human ancestors.

Two uranium isotopes are used for radiometric dating.

Uranium-lead dating is usually performed on zircon crystals (Figure below). When zircon forms in an igneous rock, the crystals readily accept atoms of uranium but reject atoms of lead. If any lead is found in a zircon crystal, it can be assumed that it was produced from the decay of uranium.

Zircon crystal.

Uranium-lead dating is useful for dating igneous rocks from 1 million years to around 4.6 billion years old. Zircon crystals from Australia are 4.4 billion years old, among the oldest rocks on the planet.

Radiometric dating is a very useful tool for dating geological materials but it does have limits:

As you've learned, radiometric dating can only be done on certain materials. But these important numbers can still be used to get the ages of other materials! How would you do this? One way is to constrain a material that cannot be dated by one or more that can. For example, if sedimentary rock A is below volcanic rock B and the age of volcanic rock B is 2.0 million years, then you know that sedimentary rock A is older than 2.0 million years. If sedimentary rock A is above volcanic rock C and it's age is 2.5 million years then you know that sedimentary rock A is between 2.0 and 2.5 million years. In this way, geologists can figure out the approximate ages of many different rock formations.

Use this resource to answer the questions that follow.

The total mass of the isotope is indicated by the numerical superscript. While the lighter isotopes ¹²C and ¹³C are stable, the heaviest isotope ¹⁴C (radiocarbon) is radioactive. This means its nucleus is so large that it is unstable. Over time ¹⁴C decays to nitrogen (¹⁴N). Most ¹⁴C is produced in the upper atmosphere where neutrons, which are produced by cosmic rays, react with ¹⁴N atoms. It is then oxidised to create ¹⁴CO₂, which is dispersed through the atmosphere and mixed with ¹²CO₂ and ¹³CO₂. This CO₂ is used in photosynthesis by plants. https://theconversation.com/explainer-what-is-radiocarbon-dating-and-how-does-it-work-9690

What is Carbon- 14 Dating? 

Reading: https://www.britannica.com/science/carbon-14-dating
https://www.radiocarbon.com/about-carbon-dating.htm
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