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      <pubDate>2018-09-29 18:08:59 UTC</pubDate>
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         <author>procesos1819</author>
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         <description><![CDATA[<div>Andrés Ghinaglia</div>]]></description>
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         <description><![CDATA[<div>Francis Ramírez</div>]]></description>
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         <author>procesos1819</author>
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         <description><![CDATA[<div>Noél Jimenez</div>]]></description>
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         <title>Demostración de las constantes de Van der Waals</title>
         <author></author>
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         <description><![CDATA[<div>Partiendo de:</div><div><a href="https://3.bp.blogspot.com/-KpZFHZZjVj0/Wspjaf1mWWI/AAAAAAAAATs/R9rAD2c8RF4ht-wzMKhLI3MTeHb8OvtGgCLcBGAs/s1600/a1.png"><figure class="attachment attachment--preview"><img src="https://3.bp.blogspot.com/-KpZFHZZjVj0/Wspjaf1mWWI/AAAAAAAAATs/R9rAD2c8RF4ht-wzMKhLI3MTeHb8OvtGgCLcBGAs/s1600/a1.png" width="316" height="93"><figcaption class="attachment__caption"></figcaption></figure></a></div><div><br></div><div>En el punto crítico termodinámico se cumple que:</div><div><a href="https://4.bp.blogspot.com/-9_j-azI594I/WspiYlGBgCI/AAAAAAAAATc/2Fs_ZzOr0NgajfXDrWb4ak5WMZ3rRaC8wCLcBGAs/s1600/a2.png"><figure class="attachment attachment--preview"><img src="https://4.bp.blogspot.com/-9_j-azI594I/WspiYlGBgCI/AAAAAAAAATc/2Fs_ZzOr0NgajfXDrWb4ak5WMZ3rRaC8wCLcBGAs/s1600/a2.png" width="398" height="120"><figcaption class="attachment__caption"></figcaption></figure></a></div><div>Al sustutir (1) en las respectivas derivadas, se obtiene:</div><div><a href="https://4.bp.blogspot.com/-5A4YQooVT74/WspnNPdkSoI/AAAAAAAAAVA/Ub-jb39QTEcw8VU49P6250LNVk5Pv4tegCLcBGAs/s1600/a1.png"><figure class="attachment attachment--preview"><img src="https://4.bp.blogspot.com/-5A4YQooVT74/WspnNPdkSoI/AAAAAAAAAVA/Ub-jb39QTEcw8VU49P6250LNVk5Pv4tegCLcBGAs/s1600/a1.png" width="413" height="201"><figcaption class="attachment__caption"></figcaption></figure></a>En términos de Pc:</div><div><a href="https://4.bp.blogspot.com/-Zr0oGmDQ-20/Wspm-BMVNsI/AAAAAAAAAU4/F668H7JSIzIsFRRR0KR80xMy-MONEp0gACLcBGAs/s1600/a1.png"><figure class="attachment attachment--preview"><img src="https://4.bp.blogspot.com/-Zr0oGmDQ-20/Wspm-BMVNsI/AAAAAAAAAU4/F668H7JSIzIsFRRR0KR80xMy-MONEp0gACLcBGAs/s1600/a1.png" width="341" height="87"><figcaption class="attachment__caption"></figcaption></figure></a></div><div><br></div><div>De (2) y (3) se obtienen a y b en términos de Tc y Vc. Despejando a de (2):</div><div><a href="https://3.bp.blogspot.com/-5JTbuYcKyzU/WspniOca5rI/AAAAAAAAAVM/Ufk35ovmYOwoBbnOXJMURVfrk5UHlvPmwCLcBGAs/s1600/a1.png"><figure class="attachment attachment--preview"><img src="https://3.bp.blogspot.com/-5JTbuYcKyzU/WspniOca5rI/AAAAAAAAAVM/Ufk35ovmYOwoBbnOXJMURVfrk5UHlvPmwCLcBGAs/s1600/a1.png" width="341" height="111"><figcaption class="attachment__caption"></figcaption></figure></a></div><div><br></div><div>Si substituimos (5) en (3), se obtiene:</div><div><br><a href="https://2.bp.blogspot.com/-AaLYJ8KLIis/Wspn_kC1f3I/AAAAAAAAAVU/5HQDv8R4OpYhZ9Zn2-GqemFCOZyE2QIlgCLcBGAs/s1600/a1.png"><figure class="attachment attachment--preview"><img src="https://2.bp.blogspot.com/-AaLYJ8KLIis/Wspn_kC1f3I/AAAAAAAAAVU/5HQDv8R4OpYhZ9Zn2-GqemFCOZyE2QIlgCLcBGAs/s1600/a1.png" width="435" height="122"><figcaption class="attachment__caption"></figcaption></figure></a></div><div>Reacomodando la ecuación:</div><div><br></div><div><a href="https://3.bp.blogspot.com/-Ho_ZnIM8Klg/WspoU1eOEEI/AAAAAAAAAVY/PKh2_jrXtXIXMrj1KB-9ec2Hl4E5ajsRQCLcBGAs/s1600/a1.png"><figure class="attachment attachment--preview"><img src="https://3.bp.blogspot.com/-Ho_ZnIM8Klg/WspoU1eOEEI/AAAAAAAAAVY/PKh2_jrXtXIXMrj1KB-9ec2Hl4E5ajsRQCLcBGAs/s1600/a1.png" width="410" height="131"><figcaption class="attachment__caption"></figcaption></figure></a></div><div>Entonces finalmente:</div><div><a href="https://3.bp.blogspot.com/-8wjK0kMWLEA/WspomdKXzxI/AAAAAAAAAVg/BmTeHn7pkzEpquK-1BlrkamTBhKkwKuewCLcBGAs/s1600/a1.png"><figure class="attachment attachment--preview"><img src="https://3.bp.blogspot.com/-8wjK0kMWLEA/WspomdKXzxI/AAAAAAAAAVg/BmTeHn7pkzEpquK-1BlrkamTBhKkwKuewCLcBGAs/s1600/a1.png" width="303" height="146"><figcaption class="attachment__caption"></figcaption></figure></a></div><div>Despejando b se obtiene:</div><div><a href="https://3.bp.blogspot.com/-i5XLAH1cMiw/WsppMn49OnI/AAAAAAAAAVs/1V-_eSZu1rkpQyy_G3IbiDizrMIqQDZ_wCLcBGAs/s1600/a1.png"><figure class="attachment attachment--preview"><img src="https://3.bp.blogspot.com/-i5XLAH1cMiw/WsppMn49OnI/AAAAAAAAAVs/1V-_eSZu1rkpQyy_G3IbiDizrMIqQDZ_wCLcBGAs/s1600/a1.png" width="148" height="89"><figcaption class="attachment__caption"></figcaption></figure></a></div><div>Para a, se sustituye (6) en (5) : </div><div><a href="https://4.bp.blogspot.com/-Wd6HgQdLt7Y/WspqCg3WmJI/AAAAAAAAAV4/cX6Tt2su2OsXwBSeCntZZH5Zc817PST2wCLcBGAs/s1600/a1.png"><figure class="attachment attachment--preview"><img src="https://4.bp.blogspot.com/-Wd6HgQdLt7Y/WspqCg3WmJI/AAAAAAAAAV4/cX6Tt2su2OsXwBSeCntZZH5Zc817PST2wCLcBGAs/s1600/a1.png" width="245" height="90"><figcaption class="attachment__caption"></figcaption></figure></a></div><div><br></div><div>A su vez, las constantes a y b también pueden ser expresadas en términos de la presión crítica partiendo de (4), concluyendo así:</div><div><br></div><div><a href="https://4.bp.blogspot.com/-JpDJRUxeLtA/Wspqj5TO2eI/AAAAAAAAAV8/Rx8aF9NTIh0oc6ExnsQ-8Nn8_Pp54efBQCLcBGAs/s1600/a1.png"><figure class="attachment attachment--preview"><img src="https://4.bp.blogspot.com/-JpDJRUxeLtA/Wspqj5TO2eI/AAAAAAAAAV8/Rx8aF9NTIh0oc6ExnsQ-8Nn8_Pp54efBQCLcBGAs/s1600/a1.png" width="241" height="189"><figcaption class="attachment__caption"></figcaption></figure></a></div><div><br><br></div>]]></description>
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         <title>Ejercicios Gases Ideales</title>
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         <title>Ejercicio %error tabla de comprensibilidad vs Viviar</title>
         <author>afgd005</author>
         <link>https://padlet.com/procesos1819/muraldeprocesos/wish/292601271</link>
         <description><![CDATA[<div>Ver Grafico en la siguiente entrada</div>]]></description>
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         <title>Grafica ejercicio %error</title>
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