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In science there are a lot of things that happen in the world that people may not always be able to explain. Things like this are known as Phenomenons. One phenomenon in particular is with an orange peel and a balloon.
This phenomena works by blowing a balloon up and cutting an orange peel. Once you have these two things all you do is squeeze the peel over the balloon and...POP! What makes this happen though?
When you squeeze the two ends of the orange peel together a chemical called limonene comes out. Limonene and the rubber balloon are both a hydrocarbon substance. When this chemical hits the rubber balloon it causes the rubber layers to dissolve and the balloon to burst.

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WASHINGTON, Aug. 9, 2018 - Orange peels contain limonene, and this chemical is the key to a party trick in which you can pop a balloon with a twist. Limonene is an exceptionally good solvent for the rubber in balloons, but some other solvents can can do it too. In this video, Reactions explains why only some chemicals can burst your bubble (or balloon): https://youtu.be/qnAhsioaHug.

Reactions is a video series produced by the American Chemical Society and PBS Digital Studios. Subscribe to Reactions at http://bit.ly/ACSReactions and follow us on Twitter @ACSReactions. For more research news, journalists and public information officers are encouraged to apply for complimentary press registration for the American Chemical Society's 256th National Meeting & Exposition, Aug. 19-23 in Boston.

The American Chemical Society, the world's largest scientific society, is a not-for-profit organization chartered by the U.S. Congress. ACS is a global leader in providing access to chemistry-related information and research through its multiple databases, peer-reviewed journals and scientific conferences. ACS does not conduct research, but publishes and publicizes peer-reviewed scientific studies. Its main offices are in Washington, D.C., and Columbus, Ohio.

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Popping balloons with style (video) - American Chemical Society

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WASHINGTON, Aug. 9, 2018 - Orange peels contain limonene, and this chemical is the key to a party trick in which you can pop a balloon with a twist. Limonene is an exceptionally good solvent for the rubber in balloons, but some other solvents can can do it too.

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https://www.youtube.com/watch?v=CvrBstj2sYU

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How to Pop a Balloon with a Orange Peel  Experiment (explained)

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I spoke with a science teacher about my phenomena on Thursday, January 13.

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How to Pop Balloons with Orange Peels! ~ With Explanation

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How to Pop a Balloon with an Orange Peel (Phenomenon)

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The NSTA Next Generation Science Standards Hub offers information, resources, news, professional learning opportunities, and expert advice in understanding and implementing the Next Generation Science Standards - NGSS

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There is a new experiment circulating the web. Check it out:

Isn't that cool? The juice from an orange peel causes a balloon to pop. When I first saw this effect I immediately thought to myself, "what is the chemistry involved in this experiment?" After quickly searching the web, I found several claims that a compound in orange peels called limonene (Figure 1) is responsible for this effect. Limonene is a hydrocarbon, which means that molecules of limonene are composed of only carbon and hydrogen atoms. Limonene is responsible for the wonderful smell of oranges, and it is a liquid at room temperature.

Figure 1 - Chemical structure of limonene

Because limonene is a hydrocarbon and hydrocarbons are non-polar molecule, one would expect limonene to be non-polar.

So what does all this chemical information have to do with balloons popping when squirted with orange peel juice? Well, balloons are made primarily of rubber. Like limonene, rubber is a hydrocarbon (Figure 2), so it's non-polar as well. It is well known by chemists that non-polar substances dissolve well in other non-polar substances (we like to say that "like dissolves like"). Therefore, when the limonene oil contacts the surface of a balloon, some of the rubber balloon dissolves in the limonene. This weakens the balloon, causing it to pop.

Figure 2 - Chemical structure of rubber (chemical name: cis-poly isoprene). The pattern of atoms seen here is repeated hundreds of times over to make a very long molecule called a polymer.

We wanted to test this claim that limonene oil is responsible for balloons popping. So we extracted some limonene oil from orange peels using a procedure published in the Journal of Chemical Education. Sure enough, limonene placed onto a balloon causes it to pop:

Interestingly, we have observed that not all balloons pop when squirted with an orange peel:

Why is it that some balloons pop in this experiment, while others do not? It has to do with chemistry, of course! The cis-poly isoprene molecules in rubber are very long molecules called polymers (see Figure 2 again). In natural rubber, these long molecular strands can readily separate from one another. Because of this molecular property, it is easy to get rubber to break into pieces or to dissolve in various solvents. This property of rubber can be changed through a process called vulcanization. During vulcanization, rubber is treated with sulfur. Vulcanization causes polymer strands to become connected by sulfur atoms (Figure 3) in what is called a cross-link. While the chemistry involved is more complex than indicated in the figure, the effect of vulcanization on rubber makes it very difficult for polymer molecules to separate from one another. Because of this, vulcanized rubber is tougher to break apart and more difficult to dissolve than normal rubber.
Figure 3 - Simplified structure of cross-linked rubber. The red arrow identifies a cross-link between two polymer strands.
Now that you know a bit about the chemistry of balloons, I think you might be able guess which balloons pop when squirted with the juice from an orange peel, and which balloons do not. Most balloons are made of vulcanized rubber ¹, presumably to keep them from breaking easily when stretched. When a balloon made of vulcanized rubber is squirted with limonene or an orange peel, it doesn't break. Water balloons are not made of vulcanized rubber ¹, because people generally want these balloons to be somewhat breakable. Because of this difference in its chemistry, a water balloon pops when squirted with limonene or orange peel juice!

We are interested to learn what types of easy-to-find, non-polar liquids can be used to cause balloons to pop. Curiously, we have tested acetone and found that it does not cause the balloons to pop. If you find some fluids that cause balloons to pop, please let us know. Also, if anyone has comments on our interpretation of the chemistry presented herein, we welcome your insights!

Notes:

1. Evidence for these claims was gained by taking infrared (IR) spectra of balloons. Peaks were consistently observed at 670cm⁻¹ (indicative of a C-S bond and therefore vulcanization) and 1010 cm⁻¹ in the IR spectra of pop-resistant balloons. However, both of these peaks were consistently absent in the IR spectra of balloons that pop when treated with non-polar compounds.

EDITOR'S NOTE - Laura Wang has expanded Tom's work by creating a QFT Task Student Handout, a Balloon Lab Design Proposal as well as a rubric (for the audience and the teacher) for the group presentation she assigns her students. Read her 8/2017 blog post, Mini-Project Sequence: Orange Peels and Polarity.

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How Does an Orange Peel Pop a Balloon? Chemistry, of Course!

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The juice from an orange peel causes a balloon to pop. When I first saw this effect I immediately thought to myself, "what is the chemistry involved in this experiment?" After quickly searching the web, I found several claims that a compound in orange peels called limonene (Figure 1) is responsible for this effect.

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MS-PS1-2 Analyze and interpret data on the properties of substances before and after the substances interact to determine if a chemical reaction has occurred.

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For the Oranges and Balloons Phenomena to occur you need one balloon and one orange peel. All you do is squeeze the two ends of the orange peel together over the aired up balloon. This causes the balloon to pop.