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He is in constant stress and fear about absolutely everything, and is distressed if something scary might happen. Piglet has a extreme case of generalized anxiety disorder.

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Eeyore with his constant pessimism  and woe-is-me attitude suffers from chronic long term  depression and could be the more serious version Dysthymia which can make sufferers have reduced appetite, energy and very low self-esteem.

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Jafar no doubt about it is considered a possible sociopath. He is extremely cruel, displaying zero empathy when he sacrifices a young boy for the realization of his goals.

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Every time he hears ticking of a clock he goes crazy and thinks of the time peter pan cut of his hand and fed it to the crocodile and now he fears that the clock with lure the crocodile to him. This is a big clue that captain hook suffers from post-traumatic stress disorder.

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Bugs Bunny shows signs of mood swings and impulsive behaviors leading to the implication that he might have Borderline Personality Disorder.

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Dexter shows many symptoms of Asperger's disorder. People with Asperger's disorder  struggle with social interactions and  and admit they are unpopular.

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Timmy Turner is rumored to have Schizophrenia because people believe that his fairly godparents that we see that he says he has, could be just his imagination.
People with Schizophrenia often see or hear things that are not really there. they also think that their imaginary friends are actually real people or beings like Timmy could be thinking or believing that he has fairies to grant his every will.

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Chuckie in the show, Rugrats, had many worries in the show. he became afraid of sandboxes after hearing the meaning of the word germ. He also believed that a watermelon was growing in his stomach after swallowing a watermelon seed. This shows to us  that Chuckie has Generalized Anxiety disorder which means that a person constantly worries about day to day activities for more than 6 months.

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Spongebob has a disorder called Williams-Beuren Syndrome . It is a disorder in development that usually results in learning problems ,attention deficit disorder, anxiety , and phobias. affected individuals usually have outgoing personalities like Spongebob. It is also worth mentioning that people with WBS usually have low muscle mass like Spongebob.

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Charlie Brown apparently has Avoidant personality disorder. Medline Plus said that people with this disorder cannot stop thinking about their shortcomings. They form relationships  with other people only if they believe they will not be rejected. In the show he has "psychiatric help" sessions with Lucy which proves that he may have this disorder.