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The Relationship Between Enthalpy , Free Energy, and Entropy is that energy is the energy associated with a chemical reaction that can do useful work. It equals the enthalpy minus the product of the temperature and entropy of the system.

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SPONTANEUS= Reaction thermodynamically capable of happening without outside energy to move it along and able to release free energy to get started and continues to occur. 

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SPONTANEUS= Reaction thermodynamically capable of happening without outside energy to move it along and able to release free energy to get started and continues to occur. 

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Non-Spontaneous: requires energy to get started and continue.  

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Non-Spontaneous: requires energy to get started and continue.  

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Work is the energy required to move an object against a force. Change in internal energy.

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Work is the energy required to move an object against a force. Change in internal energy.

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State function, a property whose value doesn't depend on the path taken to reach that specific value.

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State function, a property whose value doesn't depend on the path taken to reach that specific value.

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In a system, a reversible process remains in thermodynamic equilibrium, while an irreversible process doesn't.

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In a system, a reversible process remains in thermodynamic equilibrium, while an irreversible process doesn't.

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System, part of the universe in which observations are made. Surrounding is the rest of the universe.

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System, part of the universe in which observations are made. Surrounding is the rest of the universe.

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Entropy, measure of the disorder or randomness of a system.

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Entropy, measure of the disorder or randomness of a system.

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Enthalpy, the sum of internal energy and the product of the pressure and volume of a thermodynamic system.

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Enthalpy, the sum of internal energy and the product of the pressure and volume of a thermodynamic system.

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Energy can not be created or destroyed; it can only be converted from one form to another.

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Plants convert radiant energy into chemical energy. We use the chemical energy that we obtain from plants as kinetic energy that is latter on transformed into work.

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The Second law of thermodynamics states that as energy is transferred or transformed, more and more of it is wasted.

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The second law also describes the relationship between heat and other forms of energy, and how energy affects matter.

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Gibbs free energy of a system is a state function.

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Gibbs free energy of a system is a state function.

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The enthalpy of the system minus the product of the temperature times the entropy of the system.

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The third law of thermodynamics states the relationship between heat and other forms of energy.