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1. carboxylic acidAny of a class of organic compounds containing a carboxyl functional group—a carbon with a double bond to an oxygen and a single bond to another oxygen, which is in turn bonded to a hydrogen.
2. aldehydeAny of a large class of reactive organic compounds (R·CHO) having a carbonyl functional group attached to one hydrocarbon radical and a hydrogen atom.
3. alkaneAny of the saturated hydrocarbons—including methane, ethane, and compounds with long carbon chain known as paraffins, etc.— that have a chemical formula of the form CnH2n+2.

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* According to the IUPAC nomenclature system, an alcohol is named by dropping the terminal "-e" of the parent carbon chain (alkane, alkene, or alkyne in most cases) and the addition of "-ol" as the ending.
* Alcohols are classified as primary, secondary, or tertiary, based upon the number of carbon atoms connected to the carbon atom that bears the hydroxyl group.

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Alcoholic Drinks

The word "alcohol" in alcoholic drinks refers to ethanol (CH₃CH₂OH).

Use of ethanol as a fuel

Ethanol burns to produce carbon dioxide and water, as shown in the equation below, and can be used as a fuel in its own right or in mixtures with petrol (gasoline).

Industrial methylated spirits (meths)

Ethanol is usually sold as industrial methylated spirits which is ethanol with a small quantity of methanol added and possibly some colour.

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Colour and Odour
The lower alcohols are colourless liquids with a characteristic smell and a burning taste. However, the higher members (with more than
1212 carbons) are colourless wax-like solids.

Polarity
Alcohols are often referred to as “polar protic” solvents. What’s that about? It is one of the key properties of alcohols and the key to understanding alcohols’ physical properties

Hydrogen Bonding
The –OH–OH bond is polar in nature, develops partial negative and positive charges over the oxygen and hydrogen atoms.

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Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl g…

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What Are Alcohols? | Organic Chemistry | Chemistry | FuseSchool

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1. “Alcohol” was first found in the sixteenth century, when it implied a fine powder.

2. Alcohol takes just 6 minutes to reach the mind cells

3. There are more than 500,000 alcohol-related deaths in Russia every year.

4. Vodka is the world’s most well-known alcohol.

5. The world’s most grounded brew has a 67.5% alcohol rate.

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Learning Objective

Identify the general properties of the alcohol functional group

Key Points

Due to the presence of an -OH group, alcohols can hydrogen bond. This leads to higher boiling points compared to their parent alkanes.

Alcohols are polar in nature. This is attributed to the difference in electronegativity between the carbon and the oxygen atoms.

In chemical reactions, alcohols often cannot leave the molecule on their own; to leave, they often become protonated to water, which is a better leaving group. Alcohols also can become deprotonated in the presence of a strong base.

Terms

carboxylic acidAny of a class of organic compounds containing a carboxyl functional group-a carbon with a double bond to an oxygen and a single bond to another oxygen, which is in turn bonded to a hydrogen.

aldehydeAny of a large class of reactive organic compounds (R·CHO) having a carbonyl functional group attached to one hydrocarbon radical and a hydrogen atom.

alkaneAny of the saturated hydrocarbons-including methane, ethane, and compounds with long carbon chain known as paraffins, etc.- that have a chemical formula of the form CnH2n+2.

leaving groupIn organic chemistry, the species that leaves the parent molecule following a substitution reaction.

Alcohols are organic compounds in which the hydroxyl functional group (-OH) is bound to a carbon atom. Alcohols are an important class of molecules with many scientific, medical, and industrial uses.

Nomenclature of Alcohols

According to the IUPAC nomenclature system, an alcohol is named by dropping the terminal "-e" of the parent carbon chain (alkane, alkene, or alkyne in most cases) and the addition of "-ol" as the ending. If the location of the hydroxyl group must be specified, a number is inserted between the parent alkane name and the "-ol" (propan-1-ol) or before the IUPAC name (1-propanol). If a higher priority group is present, such as an aldehyde, ketone or carboxylic acid, then it is necessary to use the prefix "hydroxy-" instead of the ending "-ol."

Alcohols are classified as primary, secondary, or tertiary, based upon the number of carbon atoms connected to the carbon atom that bears the hydroxyl group.

The alcohol functional groupAlcohols are characterized by the presence of an -OH group, which is generally in a bent shape, like that of water.

Structure and Physical Properties of Alcohols

The structure of an alcohol is similar to that of water, as it has a bent shape. This geometrical arrangement reflects the effect of electron repulsion and the increasing steric bulk of the substituents on the central oxygen atom. Like water, alcohols are polar, containing an unsymmetrical distribution of charge between the oxygen and hydrogen atoms. The high electronegativity of the oxygen compared to carbon leads to the shortening and strengthening of the -OH bond. The presence of the -OH groups allows for hydrogen bonding with other -OH groups, hydrogen atoms, and other molecules. Since alcohols are able to hydrogen bond, their boiling points are higher than those of their parent molecules.

Alcohols are able to participate in many chemical reactions. They often undergo deprotonation in the presence of a strong base. This weak acid behavior results in the formation in an alkoxide salt and a water molecule. Hydroxyl groups alone are not considered good leaving groups. Often, their participation in nucleophilic substitution reactions is instigated by the protonation of the oxygen atom, leading to the formation a water moiety-a better leaving group. Alcohols can react with carboxylic acids to form an ester, and they can be oxidized to aldehydes or carboxylic acids.

Alcohols have many uses in our everyday world. They are found in beverages, antifreeze, antiseptics, and fuels. They can be used as preservatives for specimens in science, and they can be used in industry as reagents and solvents because they display an ability to dissolve both polar and non-polar substances.

Licenses and Attributions

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Learning Objective Identify the general properties of the alcohol functional group Key Points Due to the presence of an -OH group, alcohols can hydrogen bond. This leads to higher boiling points compared to their parent alkanes. Alcohols are polar in nature.