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The core gets hotter and more dense as it goes towards the center, and once iron forms it can no longer handle the temperatures and the core implodes. Then, all the surrounding layers go off into space and all that is left is a neutron star.

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Here's a motion graphics piece I did this year in After Effects. Directed, edited, narrated by Christian Rush

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The layers of a star before the supernova

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This is supernova 1987a, an example of a type II supernova